Spezialchemie - Spezialchemie

Oxazolidine Building Blocks

All oxazolidines listed below have a purity of ≥ 95% (GC/LC, pure by 1H NMR). Compounds are configurationally stable at room temperature over several days, at least. For having in stock, we recommend storage at ≤ -20°C under exclusion of light.

 
   
 

(–)-(S)-3-tert-Butyl 4-methyl 2,2-dimethyloxazolidine-3,4-dicarboxylate
· (–)-(S)-N-Boc-methyl 2,2-dimethyloxazolidine-4-carboxylate
·
(–)-(S)-3-(tert-Butoxycarbonyl)-4-methoxycarbonyl-2,2-dimethyloxazolidine


 

(+)-(R)-3-tert-Butyl 4-methyl 2,2-dimethyloxazolidine-3,4-dicarboxylate
· (+)-(R)-N-Boc-methyl 2,2-dimethyloxazolidine-4-carboxylate
· (+)-(R)-3-(tert-Butoxycarbonyl)-4-methoxycarbonyl-2,2-dimethyloxazolidine


 

(–)-(S)-tert-Butyl 4-formyl-2,2-dimethyloxazolidine-3-carboxylate
· (–)-(S)-N-Boc-2,2-dimethyloxazolidine-4-carbaldehyde
· (
)-(S)-3-(tert-Butoxycarbonyl)-4-formyl-2,2-dimethyloxazolidine
· (
)-(S)-Garner Aldehyde

top building block  

 

(+)-(R)-tert-Butyl 4-formyl-2,2-dimethyloxazolidine-3-carboxylate
· (+)-(R)-N-Boc-2,2-dimethyloxazolidine-4-carbaldehyde
· (+)-(R)-3-(tert-Butoxycarbonyl)-4-formyl-2,2-dimethyloxazolidine
· (+)-(R)-Garner Aldehyde

top building block  

 

(–)-(R)-tert-Butyl 4-ethynyl-2,2-dimethyloxazolidine-3-carboxylate
· ()-(R)-N-Boc-4-ethynyl-2,2-dimethyloxazolidine
· ()-(R)-3-(tert-Butoxycarbonyl)-4-(1’-tert-butyl-4’-hydroxybuta-1’,2’-dienyl)-2,2-dimethyloxazolidine


 

()-(S)-3-Benzyl 4-methyl 2,2-dimethyloxazolidine-3,4-dicarboxylate
·
(–)-(S)-N-Cbz-methyl 2,2-dimethyloxazolidine-4-carboxylate
· (
)-(S)-3-Benzyloxycarbonyl-4-methoxycarbonyl-2,2-dimethyloxazolidine


 

(+)-(R)-3-Benzyl 4-methyl 2,2-dimethyloxazolidine-3,4-dicarboxylate
·
(+)-(R)-N-Cbz-methyl 2,2-dimethyloxazolidine-4-carboxylate
· (+)-(R)-3-Benzyloxycarbonyl-4-methoxycarbonyl-2,2-dimethyloxazolidine


 

()-(S)-Benzyl 4-formyl-2,2-dimethyloxazolidine-3-carboxylate
· (
)-(S)-N-Cbz-2,2-dimethyloxazolidine-4-carbaldehyde
· (
)-(S)-3-Benzyloxycarbonyl-4-formyl-2,2-dimethyloxazolidine


 

(+)-(R)-Benzyl 4-formyl-2,2-dimethyloxazolidine-3-carboxylate
· (+)-(R)-N-Cbz-2,2-dimethyloxazolidine-4-carbaldehyde
· (+)-(R)-3-Benzyloxycarbonyl-4-formyl-2,2-dimethyloxazolidine


 

()-(S)-Methyl 2,2-dimethyl-3-tosyloxazolidine-4-carboxylate
·
(–)-(S)-N-Tosyl-methyl 2,2-dimethyloxazolidine-4-carboxylate
· (
)-(S)-3-(Toluol-4-sulfonyl)-4-methoxycarbonyl-2,2-dimethyloxazolidine


 

(+)-(4S,2’R)-(tert-Butoxycarbonyl)-4-(3’-phenyl-2’,5’-dihydrofuran-2’-yl)-2,2-dimethyloxazolidine

intermediate in synthesis of phenyl-containing natural product derivatives


 215-3-1  

(R)-Benzyl 4-[4-butyl-1-(2-chloroethyl)-1H-pyrrol-2-yl]-2,2-dimethyloxazolidine-3-carboxylate
· (-)-(R)-N-Cbz-4-[4-butyl-1-(2-chloroethyl)-1H-pyrrol-2-yl]-2,2-dimethyloxazolidine
· (-)-(R)-3-(Benzyloxycarbonyl)-4-[4’-butyl-1’-(2’’-chlorethyl)-1H-pyrrol-2-yl]-2,2-dimethyloxazolidine

part of a redox equilibrium

If you have any questions about any of the compounds or their derivatives and stereoisomers please feel free to get in touch with us.